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Complete All Scenarios 500G
There are 40 challenges to complete this game. 33 to start with before you unlock the final 7. Some of these are easy, and some will make you want to scream. Patience is needed to complete these for certain, but a very rewarding 500 points awaits you!

If you struggle, you can always alter the opponent's team settings before starting the game. Do this at the initial game main menu.

Win the World Cup 250G
To do this, all you need to do is start a World Cup and then carry on to win the tournaments. See the forums for tips if you need any, but you shouldn't have any problems. Pick a decent team to start with- Brazil, Argentina, France or England are the best odds.

Qualify for The World Cup 150G
Instead of going straight for the World Cup, play through the qualifying tournament. The European teams have less matches to play and tend to have easier opponents, so id recommend England or France for this one.

Beat the Host Nation 50G
You need to do this in the world cup final stage - so you may be able to do it when completing the World Cup. If not, once you have won the World Cup, set up a friendly against Germany and make sure that it's set to World Cup Final, and a 90-minute match.

Complete a Scenario 50G
Complete any of the 40 Scenarios. Look at the description to see if it sounds like fun!

The easiest one in my opinion is the scenario called "Romanian Lottery". This is just a penalty shootout between Romania and Sweden that you simply must win.