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Acquire all sorceries.

There are 34 sorceries in the game. Most can be bought or found but some can only be traded for boss souls or acquired from Covenants. To get them all you will also need to recruit Orbeck of Vinheim and Karla the Witch (do not kill either of them).

Orbeck is found in the Road of Sacrifices in the building before the Crystal Sage boss - you must have Int of at least 10 then accept his help and he relocates to Firelink Shrine.

IMPORTANT: If you recruit Orbeck and then kill any FOUR bosses before giving him even one scroll he will leave, so make sure that doesn't happen.

Karla is found in Irythrill Dungeon, in the room with a host of jailers, but you need to get the Jailers Key from the Profaned Capital. In the toxic swamp area climb the ladder up the building here and follow the roof to the left and up some stairs, then follow this path ahead to find the key on a corpse. Go back and free her to make her move to Firelink Shrine.

You then need the following scrolls to give to Orbeck of Vinheim to unlock spells to buy:

Sage's Scroll - Found in the Road of Sacrifices near the Keep Ruins bonfire. Look left after coming out of the tower (towards the ramp) and it is across the swamp in an area with a bunch of dead mushrooms, guarded by enemies.

Golden Scroll - Found in the Road of Sacrifices from the Farron Keep bonfire. You need to follow the right wall all the way through the poison swamp. The scroll is in a cave at the end of that wall guarded by some basilisks.

Logan's Scroll - Found in the poison swamp in Profaned Capital, climb the ladder up the building here and follow the roof around to some stairs. Head up and look to your right to see an NPC on the roof, kill him and he drops this item.

Crystal Scroll - When you arrive in the Grand Archives a Crystal Sage will spawn ahead of you, do enough damage and he warps away. Keep on attacking him every time you find him until he dies, then he will drop this.

The spells are as follows:

Soul Arrow - Sold by Yoel of Londor for 1000 souls, Sold by Yuria of Londor for 1000 souls, Sold by Orbeck of Vinheim for 1000 souls.

Great Soul Arrow - Sold by Orbeck of Vinheim for 3000 souls

Heavy Soul Arrow - Sold by Yoel of Londor for 2000 souls, Sold by Yuria of Londor for 2000 souls, Sold by Orbeck of Vinheim for 2000 souls.

Great Heavy Soul Arrow - Sold by Orbeck of Vinheim for 4000 souls.

Farron Dart - Sold by Yoel of Londor for 1000 souls, Sold by Orbeck of Vinheim for 500 souls.

Great Farron Dart - Sold by Orbeck of Vinheim for 2000 souls (Requires Sage's Scroll).

Farron Hail - Sold by Orbeck of Vinheim for 5000 souls (Requires Sage's Scroll).

Homing Soulmass - Sold by Orbeck of Vinheim for 6000 souls (Requires Logan's Scroll).

Homing Crystal Soulmass - Sold by Orbeck of Vinheim for 18,000 souls (Requires Crystal Scroll).

Crystal Hail - Obtained by Soul of a Crystal Sage Transposition.

Soul Spear - Sold by Orbeck of Vinheim for 5000 souls (Requires Logan's Scroll).

Crystal Soul Spear - Sold by Orbeck of Vinheim for 15,000 souls (Requires Crystal Scroll).

White Dragon Breath - Obtained by Soul of Consumed Oceiros Transposition.

Soul Stream - Found in Lothric Castle in the Grand Archive. Near the top level pull a lever to reveal a hidden room with a Boreal Knight. This is on a corpse just past him.

Soul Greatsword - Sold by Yoel of Londor for 5000 souls, Sold by Yuria of Londor for 5000 souls, Sold by Orbeck of Vinheim for 5000 souls.

Farron Flashsword - Sold by Orbeck Of Vinheim for 3000 souls.

Magic Weapon - Sold by Yoel of Londor for 4500 souls, Sold by Yuria of Londor for 4500 souls, Sold by Orbeck of Vinheim for 3000 souls.

Great Magic Weapon - From the Farron Keep Perimeter bonfire, turn around and head towards the shortcut gate to Road of Sacrifices (past the Black Knight and large Crystal Lizard). The spell will be on a corpse by the gate.

Crystal Magic Weapon - Sold by Orbeck of Vinheim for 10,000 souls (Requires Crystal Scroll).

Magic Shield - Sold by Yoel of Londor for 4500 souls, Sold by Yuria of Londor for 4500 souls, Sold by Orbeck of Vinheim for 3000 souls.

Great Magic Shield - Found in Irithyll Dungeon

Spook - Sold by Orbeck Of Vinheim for 2000 souls.

Aural Decoy - Sold by Orbeck of Vinheim for 2000 souls.

Pestilent Mercury - Sold by Orbeck Of Vinheim for 1000 souls.

Cast Light - Sold by Orbeck Of Vinheim for 1000 souls (Requires Golden Scroll).

Repair - Sold by Orbeck of Vinheim for 2000 souls (Requires Golden Scroll).

Hidden Weapon - Sold by Orbeck of Vinheim for 1500 souls (Requires Golden Scroll).

Hidden Body - Sold by Orbeck of Vinheim for 3000 souls (Requires Golden Scroll).

Chameleon (MISSABLE) - Can be found in the Church of Yorshka bonfire in Irithyll of the Boreal Valley during Anri's questline. The spell will drop from an assassin disguised as a statue. DO NOT KILL THE STATUE IF YOU WANT THE USURPTION OF FIRE ENDING. Instead wait until you get to Darkmoon Tomb (just before Anor Londo) and speak to the pilgrim then interact with Anri's corpse. Head back to where the pilgrim was and this spell will be on the corpse.

Twisted Wall of Light - Sold by Orbeck of Vinheim for 6000 souls (Requires Golden Scroll).

Deep Soul - Obtained from the Soul of Deacons of the Deep Transposition.

Great Deep Soul - Reward for reaching rank 1 in the covenant Aldrich Faithful. The Covenant is located behind an illusionary wall on the left of the building you enter after crossing the field of dead (and not so dead) giants after the Pontiff boss. You need to kill two of the wolf/croc enemies down here to access it. Then you need 10 Human Dregs - one is on the floor of this room, the rest can be acquired by invading as a covenant member OR farmed from the Deacons of the Deep in the area above where the giants were or in Anor Londo. Use the Covetous Gold Serpent Ring, Symbol of Avarice (found from minics) and Rusted Coins. Drop rate is roughly one in thirty with this combo.

Affinity - Sold by Karla for 15,000 souls.

Dark Edge - Sold by Karla for 8,000 souls.