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The first thing you want to do is go to multiplayer and get one kill to get that trophy out of the way. then you can load the pappy 45 save to get all other multiplayer trophies. you need to do one of each action to get them to pop. after you get all the kills from the main menu hit options button and then triangle to prestige and earn the top rank trophy, and hopefully the prestige for the first time trophy.

Next load up the platinum save and complete the final level of each chapter for those trophies, check guide for specifics, and complete any challenge with gold or better for the coin collector trophy. I suggest the first challenge. there are a few tricky trophies you will need to get, like get a kill with 1% health in multiplayer but if you keep trying you will get it.