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There are a total of 8 Hub locations that you must visit outside of the story mode. After you have completed the story head to space and then go to all 8 locations. The trophy will unlock as soon as you arrive at the 8th one. The 8 Hub locations that you must visit are:

1) Manhattan
2) Malibu
3) Asgard
4) Barton's Farm
5) Sokovia
6) South Africa
7) Washington D.C.
8) S.H.I.E.L.D. Base

Note: This trophy seems to be a little off for some people, it seems that you have to visit all of the locations in one sitting for the trophy to unlock. If you are having trouble getting this trophy to unlock then go to each one back to back and it should unlock.

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